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Flotation and adsorption characteristics of the hematite-dodecylamine-starch system

机译:赤铁矿-十二烷基胺-淀粉体系的浮选和吸附特性

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摘要

Simultaneous adsorption of 3H-dodecylamine and 14C-starch onto hematite was investigated by two-channel liquid scintillation counting. Floatability of the resultant hematite was determined using a new type of laboratory test cell. Amine adsorption followed a Freundlich type isotherm, T = KC^n , n varying with pH and starch concentration. Adsorption increased with pH, especially at pH 8 - 10, and was enhanced by starch at low pH. Starch decreased amine adsorption at high pH. Starch adsorption increased with concentration and rose with amine concentration to 10^-4 molar. Higher amine concentrations lowered starch adsorption. Floatability increased with amine concentration up to 10^-3 molar and fell at 10^-2 molar amine. Maximum flotation was achieved in slightly alkaline solution. Starch was most effective as a depressant at high and low pH but the maximum floatability value was little affected. Starch produced a shift of the maximum floatability peak to higher pH levels. An explanation, based on amine-starch complexing, is proposed.
机译:通过两通道液体闪烁计数研究了3H-十二烷基胺和14C-淀粉同时吸附在赤铁矿上。使用新型的实验室测试池确定了生成的赤铁矿的漂浮性。胺吸附遵循Freundlich型等温线,T = KC ^ n,n随着pH和淀粉浓度的变化而变化。吸附随pH的增加而增加,特别是在pH 8-10的情况下,而淀粉在低pH的条件下会增强。淀粉在高pH下降低了胺吸附。淀粉的吸附量随浓度的增加而增加,随胺浓度的增加而上升至10 ^ -4摩尔。较高的胺浓度降低了淀粉的吸附。随胺浓度的增加,直到10 ^ -3摩尔胺,漂浮性增加,而当胺浓度为10 ^ -2摩尔时,漂浮性下降。在弱碱性溶液中实现了最大浮选。淀粉在高pH和低pH下最有效作为抑制剂,但最大漂浮性值几乎不受影响。淀粉产生了最大浮性峰向较高pH值的偏移。提出了基于胺-淀粉络合的解释。

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  • 作者

    Partridge, Anthony C.;

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  • 年度 1970
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  • 原文格式 PDF
  • 正文语种 en
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